Notify can be triggered with stored procedures to send payloads related to changes to a table. It can be set up to send the id of a row that was inserted or updated, for example. (But WAL replication is usually better for this)
Broadcasting the id to a lot of workers is not useful, only one of them should work on the task. Waking up the workers to do a SELECT FOR UPDATE .. SKIP LOCKED is the trick. At best the NOTIFY payload could include the kind of worker that should wake up.
